Recent advances in battery energy storage technologies enable increasing number of photovoltaic-battery energy storage systems (PV-BESS) to be deployed and connected with current power grids. The reliable and efficient utilization of BESS imposes an obvious technical challenge which needs to be urgently addressed. In this paper, the optimal operation of PV-BESS based power plant is investigated. The operational scenarios are firstly partitioned using a self-organizing map (SOM) clustering based approach. The revenue optimization model is adopted for the PV-BESS power plants to determine the optimal operational modes under typical conditions for a set of considerations, e.g. power generation revenue, assessing rewards/penalties as well as peak shaving/valley filling revenue. The solution is evaluated through a set of case studies, and the numerical result demonstrates the effectiveness of the suggested solution can optimally operate the BESS with the maximal revenue.