Electric vehicles present a fast-growing trend due to their outstanding energy conservation and emission reduction characteristics. As significant support for electric vehicles, the actual planning and operation of the charging service network determine the advancement prospects of electric vehicles. Firstly, in light of the elements and development formation of the charging service network, electric vehicle clusters’ scale evolution method and charging demand forecasting under the influence of multiple factors are highlighted. Secondly, the coupled relationship among the charging service, power distribution, and transportation network is analyzed. A comprehensive evaluation system under the integration of three networks is established to evaluate the performance of the coupled networks. The development of the charging infrastructure planning method is systematically portrayed, and collaborative network planning method of charging service as well as power and transportation networks is proposed. In addition, the price mechanism and operation strategy of the charging service network is analyzed; the charging service price formulation strategy affected by multiple factors is suggested. Finally, the new business model of charging service network based on technologies such as the ubiquitous power Internet of Things (IoT) is addressed. This work is supported by National Natural Science Foundation of China (No. 51807127).